One of the most fundamental things we can observe is that when we heat a material up it expands. The purple atoms are the manganese and the silver atoms are nickel. This happens with a large increase of the crystal’s volume, and the penetration of the fluid inside the framework of these new structures!ĭetails of the crystal structure of a low thermal expansion alloy (Manganese Nickel) investigated by Yokoyama et al at the National Institute for Materials Science in Japan.
With some simple fluids, such as water and methanol, compression can lead to other structures from the family of four-connected nets. In 2013, it was shown that the behavior at high pressure (a few gigapascal) depends on the nature of the fluid used for compression. Moreover, these net have a very familiar motif: they have the same structure as diamond! (with Zn taking the place of carbon, and C–C bonds being replaced by Zn–C–N–Zn linkage).Īnd there is more! Though the structure at ambient conditions described above has been known since 1945, the behavior of zinc cyanide under pressure remained a mystery until very recently. You can see it on the picture above, where one of the framework has been colored in yellow, while the other one is purple (Zn) and black (C and N). two three-dimensional frameworks with no bonds between them, but “interlocked” within each other. Zeolitic materials (previously featured here!) are a very wide family of such structures, with 216 different frameworks known to date.įrom this infinite array of possible structure, zinc cyanide adopts a particularly interesting one. This is a geometry common to many crystals, though the results show endless variety: mathematically, there is an infinite number of ways to arrange such tetrahedra in space, called four-connected nets. In zinc cyanide, or Zn(CN)2, each zinc is surrounded by four cyanide ligands, linking it to neighboring zinc atoms. Not very exciting… Indeed, its beauty comes not from its uses, but from the crystallographic structure itself. Zinc cyanide is used for electroplating of zinc, and as a catalyst for a few reactions in organic chemistry.
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